In situ degradation of low-density polyethylene film in irrigation maize field: Thickness-dependent effect

Thickness of low-density polyethylene (LDPE) film might determine its mechanical strength, clean production and soil health. Yet, this issue is little understood. In situ aging effects were evaluated in LDPE films with the thickness of 0.006 mm, 0.008 mm, 0.010 mm and 0.015 mm in maize field. The data showed that maximum tensile force (TFmax), maximum tensile strength (TSmax) and elongation at break (EAB) were massively lowered with increasing thickness after aging. The greatest and lowest reduction magnitude of EAB was 27.6 % and 11.2 % in 0.006 mm and 0.015 mm films respectively. Also, the melting point (Tm) and crystallinity (Xc) under Differential Scanning Calorimeter (DSC) tended to decline with the increasing thickness. Moreover, the peak intensity of crystalline regions tended to transfer and concentrate on the amorphous regions, and such tendency became more pronounced in the thin films. Interestingly, there existed a pronounced distinct thickness-dependent effects on soil bulk density (SBD) and soil water-stable aggregate proportion. Thick plastic film mulching increased SBD but reduced the proportion of macroaggregates (mainly referred to 0.015 mm and 0.010 mm). In addition, thick film mulching slightly reduced the levels of soil organic carbon (SOC) and total nitrogen (TN), but significantly promoted the contents of soil labile C and N. Particularly, it significantly promoted above- & under-ground biomass of maize across two growing seasons (p < 0.05). To sum up, thickening LDPE film may act as a promising solution to improve LDPE film residue recycling, while benefiting for higher productivity. However, thick film mulching may cause a certain adverse impact on soil structure, and further investigations would be needed in the future.