Photoluminescence Investigations and Band Gap Engineering in Environment Friendly ZnO Nanorods: Enhanced Water Treatment Application and Defect Model

The inadvertent discharge of industrial effluents, mainly textile, contributes to the complex contamination load in water bodies. Textile dyes are the critical effluents and recalcitrant to traditional remediation procedures. Therefore, energy viable and environment friendly solutions are needed. In this study, we have synthesized zinc oxide nanorods (NRs) at various temperatures using modified thermal decomposition and evaluated its photocatalytic activities. Field effect scanning electron microscopy has confirmed rod-like morphology till TS = 500 °C and spherical morphology from TS = 600 °C onward. Photoluminescence spectra have shown a prominent defect peak in the synthesized ZnO, except for the NRs synthesized at 300 °C. Synthesized ZnO NRs and NPs have been employed to degrade crystal violet (CV) and congo red (CR) dyes. ZnO NRs have shown impressive photocatalytic performance with faster treatment time as compared to the earlier reports. Synthesis parameters are well correlated with the observed high efficiency and the band gap tailoring. Based on our findings, for the first time, we have proposed (i) defect model correlating synthesis parameters with defect states, (ii) systematic correlation of defect states with photocatalytic efficiency, and (iii) ZnO nanorods synthesized at 300 °C via an improved synthesis method as a promising photocatalytic solution to degrade the CV and CR dyes in contaminated water.