鲁米诺
催化作用
化学发光
化学
超氧化物
光化学
电子顺磁共振
氧气
X射线光电子能谱
无机化学
分解
离子
碳纤维
材料科学
物理化学
化学工程
核磁共振
有机化学
酶
复合材料
工程类
物理
复合数
出处
期刊:Carbon
[Elsevier]
日期:2015-02-01
卷期号:82: 459-469
被引量:56
标识
DOI:10.1016/j.carbon.2014.10.089
摘要
This paper reports for the first time the chemiluminescence (CL) of luminol in the absence of added oxidant with carbon dots (CDs) as the catalyst. By means of CL spectra, UV–vis spectra, electron spin resonance spectra, Fourier transform infrared and X-ray photoelectron spectra, the possible CL reaction mechanism is proposed. The CL luminophor was still 3-aminophthalate, the CL enhancement of luminol system was supposed to originate from the intrinsic catalytic activity of CDs, which can efficiently catalyze the decomposition of dissolved oxygen to generate superoxide radical anion in luminol solution. Then, the resulting superoxide radical anion reacted with luminol to cause CL emission. Furthermore, the effects of size and surface states on the catalytic activity of CDs were investigated. The results suggested that the catalytic activity of CDs are mainly affected by the surface states, and the size of CDs display little influence on the catalytic activity of CDs. Therefore, the catalytic activity of CDs can be tuned by modulating functional groups on the surface of CDs, which sheds new light on the characteristic of CDs.
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