化学
铜
吸附
吸收(声学)
盐(化学)
无机化学
多孔性
分析化学(期刊)
高分子化学
核化学
物理化学
有机化学
复合材料
材料科学
作者
Wasuke Mori,Fumie Inoue,Keiko Yoshida,Hirokazu Nakayama,Satoshi Takamizawa,Michihiko Kishita
出处
期刊:Chemistry Letters
[Oxford University Press]
日期:1997-12-01
卷期号:26 (12): 1219-1220
被引量:160
摘要
Abstract Copper(II) terephthalate absorbs a large amount of gases such as N2, Ar, O2, and Xe. The maximum amounts of absorption of gases were 1.8, 1.9, 2.2, and 0.9 mole per one mole of the copper(II) salt for N2, Ar, O2, and Xe, respectively, indicating that the gases were not adsorbed on the surface but occluded within the solid. The porous structure of copper(II) terephthalate, in which the gas is occluded, is deduced from the temperature dependence of magnetic susceptibilities and the linear structure of terephthalate.
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