弹性体
聚合物
高分子化学
自愈
玻璃化转变
化学工程
动态力学分析
作者
Jin Hu,Ruhan Yang,Li Zhang,Ying Chen,Xinxin Sheng,Xinya Zhang
出处
期刊:Polymer
[Elsevier]
日期:2021-04-22
卷期号:222: 123674-
被引量:4
标识
DOI:10.1016/j.polymer.2021.123674
摘要
Abstract Intrinsic self-healing materials designed through the incorporation of noncovalent interactions or dynamic covalent bonds are prized for their ability to recover from mechanical damages. However, they often suffer from deteriorated mechanical property due to the increased chain mobility. In this work, we reported a high-strength, colorless transparent self-healing polyurethane elastomer through dynamic crosslinking of reversible phenol-carbamate bonds. Tetrabromobisphenol A (TBBPA) and propyl gallate (PG) were used as the dynamic chain extender and dynamic crosslinking agent, respectively. They both can be effectively deblocked at mild temperatures ensuring that the self-healing efficiency is not affected by the material formulation. The mechanical properties can be tailored in a wide range by varying the crosslink density and hard segment content, and their combination uniquely determines the material formulation. The phenol-carbamate based polyurethane (PPU) with a hard segment of 60% and a crosslink density ν of 0.5 mmol cm−3 exhibited a tensile strength up to 46.4 MPa at the break strain of 615% and displayed high elastic resilience. In the meantime, it could be fully healed (ησ = 93%) with 2 h of heating at 100 °C after completely cut off. After recycled three times, it still maintained 80% of its original tensile strength. The structural rigidity of the crosslinker PG and the highly reversible phenol-carbamate bond play a crucial role in strengthening the mechanical strength while maintaining the self-healing efficiencies at elevated temperatures. This work provides a feasible strategy to prepare mechanically robust crosslinked polyurethane elastomer with high self-healing efficiency in a cost-effective manner.
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