Serendipitous synthesis of 2-alkenyl- and 2-aryl-4-thiazolidinones using dithiodiglycolic anhydride

Dithiodiglycolic anhydride undergoes an efficient formal cycloaddition with imines to afford functionalized 4-thiazolidinones, without complications arising from the anhydride-imine reaction or the sulfa-Michael reaction (in the case of 1,3-azadienes).