Bioinspired Robust Gas‐Permeable On‐Skin Electronics: Armor‐Designed Nanoporous Flash Graphene Assembly Enhancing Mechanical Resilience

Abstract Soft on‐skin electrodes play an important role in wearable technologies, requiring attributes such as wearing comfort, high conductivity, and gas permeability. However, conventional fabrication methods often compromise simplicity, cost‐effectiveness, or mechanical resilience. In this study, a mechanically robust and gas‐permeable on‐skin electrode is presented that incorporates Flash Graphene (FG) integrated with a bioinspired armor design. FG, synthesized through Flash Joule Heating process, offers a small‐sized and turbostratic arrangement that is ideal for the assembly of a conductive network with nanopore structures. Screen‐printing is used to embed the FG assembly into the framework of polypropylene melt‐blown nonwoven fabrics (PPMF), forming a soft on‐skin electrode with low sheet resistance (125.2 ± 4.7 Ω/□) and high gas permeability (≈10.08 mg cm⁻ 2 h⁻¹). The “armor” framework ensures enduring mechanical stability through adhesion, washability, and 10,000 cycles of mechanical contact friction tests. Demonstrating capabilities in electrocardiogram (ECG) and electromyogram (EMG) monitoring, along with serving as a self‐powered triboelectric sensor, the FG/PPMF electrode holds promise for scalable, high‐performance flexible sensing applications, thereby enriching the landscape of integrated wearable technologies.