Two-dimensional (2D) quasi-living crystallization-driven self-assembly of polyethylene-b-hyperbranched polyglycidol diblock copolymers in solution

The crystalline nucleation, micellization, two-dimensional (2D) growth kinetics of PE- b-hb PG copolymers during cooling and isothermal crystallization were monitored by TEM, AFM and in situ DLS, and the mechanism of the 2D living growth was elucidated.