Experimental study on the development mode and evolution mechanism of sodium silicate solidified sand under different temperatures and curing paths

固化(化学) 材料科学 复合材料 抗压强度 硅酸钠 扫描电子显微镜 水化反应 水泥
作者
Yitian Xu,Tao Wei,Guoqing Chen,J Ma,Ming Yan
出处
期刊:Construction and Building Materials [Elsevier BV]
卷期号:409: 134073-134073
标识
DOI:10.1016/j.conbuildmat.2023.134073
摘要

Water glass, which can be cured by rapid dehydration, is an ideal environmentally friendly material for engineering grouting solidification and ecological environment restoration. The curing efficiency of water glass at room temperature was low, the curing mechanism and strength characteristics at high temperature were not clear, and the engineering applicability and optimal curing methods were to be explored. In this paper, 10 curing paths were designed within 100 °C. The mechanical and acoustic characteristics of water glass-cured sandy soils were tested by uniaxial compressive tests and acoustic emission (AE). The relationship between strength, wave velocity and curing age was established based on the “logistics” model. The characteristic parameter “Q” value was proposed based on the AE characteristic value. Combined with the results of scanning electron microscopy (SEM), the solidification evolution process was revealed in terms of gel structure, crystal morphology and pore space. The process of water glass curing sandy soil was divided into a “strength rising period” and a “strength deterioration period”. The enhancement and weakening effects of high temperature on the gel layer were stronger than those at room temperature. The longer the room temperature curing time is, the weaker the effect of high temperature on the specimen. After high-temperature curing, the maximum strength of the specimens increased by 107.85 %, and the strength growth rate and strength deterioration rate increased by 586.34 % and 3738.79 %, respectively. The conversion rate of the gel under high temperature conditions determined the strength of the specimen. The rate of strength deterioration of the specimen was determined by the hardening effect of the undehydrated gel and the excessive dehydration effect of the rigid gel.
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