钴
催化作用
醛
光催化
化学
酒精氧化
选择性
酒
组合化学
连续流动
有机化学
物理
机械
作者
Jia Ding,Shuaishuai Luo,Yuanli Xu,Qing An,Yi Yang,Zhiwei Zuo
摘要
A synergistic photocatalytic system using a bisphosphonium catalyst and a cobalt catalyst has been developed, enabling the selective oxidation of benzylic alcohols under oxidant-free and environmentally benign conditions. High efficiencies have been obtained for a variety of alcohol substrates, and exclusive selectivity for aldehyde products has been achieved across the board. Furthermore, this photocatalytic system proved to be efficient when performed under continuous-flow conditions, even using a simple and easily assembled continuous-flow setup.
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