Alteration and progressive degradation of plastic waste in a polish operational landfill analysed over 60 years

Polyethylene (PE) plastic waste poses an environmental challenge. To explore degradation processes over an extended period, a 60-year study was conducted at an operational landfill in Poland. This landfill, in use since 1960, offers a unique chronological representation of degradation potential due to distinct layering of waste without mixing. Employing analytical techniques, such as Fourier Transform Infrared Spectroscopy (FTIR), Differential Scanning Calorimeter (DSC), Scanning Electron Microscopy (SEM), and fluorescence microscopy, plastic waste samples were examined over decades. FTIR identified and characterized the samples, revealing traces of degradation. DSC indicated reduced crystallinity, implying diminished chemical stability. SEM showcased plastic fragment liberation, confirming degradation. Fluorescence microscopy and SEM confirmed microorganisms’ involvement, forming colonies around areas of strong delamination. The study provides insights into plastic waste dynamics, emphasizing microorganisms and hydrolytic processes in landfills. This contributes to understanding over 60 years period and underscores the need for waste management to handle plastic pollution effectively. Polyethylene waste progressively decomposed over the past 60 years in a process involving microbial as well as physical and chemical degradation, with a total term of degradation of 670 years, according to analyses of a layered landfill site in Poland.