量子产额
光致发光
钙钛矿(结构)
材料科学
量子效率
光电子学
量子点
纳米晶
光化学
带隙
纳米技术
结晶学
化学
光学
荧光
物理
作者
Chen Cheng,Tongtong Xuan,Wenhao Bai,Tianliang Zhou,Fan Huang,An Xie,Le Wang,Rong‐Jun Xie
出处
期刊:Nano Energy
[Elsevier]
日期:2021-07-01
卷期号:85: 106033-106033
被引量:71
标识
DOI:10.1016/j.nanoen.2021.106033
摘要
Removing long-chain ligands on the surface of perovskite nanocrystals (NCs) is a promising strategy to facilitate charge transport towards a high-performance perovskite light-emitting diode (PeLED). However, perovskite NCs, especially CsPbI3 NCs, tend to decompose in the ligand removal procedure due to their poor stability of perovskite NCs and high polarity of solvents. Here, we report Sr2+-doped CsPbI3 NCs that were synthesized by a modified hot injection method. These NCs show enhanced stability and near-unity photoluminescence quantum yield (PLQY, 99.8%). More importantly, the CsPbI3:Sr2+ NCs still maintain a high PLQY (97.5%) after removing surface ligands by a polar solvent (ethyl acetate, EA). Furthermore, a mixture of EA and octane was used to prepare smooth and dense CsPbI3:Sr2+ NC films with an exceedingly high PLQY of 73.2% and a high stability under ambient conditions. Finally, the red-emitting CsPbI3:1.8% Sr2+ PeLEDs demonstrate a world-record peak external quantum efficiency (EQE) of 17.1%.
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