纳米片
光催化
光降解
材料科学
氮化碳
X射线光电子能谱
石墨氮化碳
碳纤维
量子点
离域电子
化学工程
光化学
纳米技术
化学
有机化学
催化作用
复合材料
复合数
工程类
作者
Yixuan Wang,Lin Chen,Xiaoli Zhao,Huimin Song,Fengting He,Siwei Cheng,Bin Zheng,Chaocheng Zhao,Jinqiang Zhang,Xiaoguang Duan,Yang Liu,Hyoyoung Lee,Hongqi Sun,Shuaijun Wang,Shaobin Wang
出处
期刊:Carbon
[Elsevier]
日期:2023-02-01
卷期号:204: 284-294
被引量:14
标识
DOI:10.1016/j.carbon.2022.12.063
摘要
Limited transport and migration of photoinduced charges in polymeric carbon nitride (g-C3N4) within the planar layers remain a great challenge for achieving favorable photocatalysis. Herein, phosphorus-doped carbon quantum dots (PCDots) implanted intra-layer carbon nitride nanosheet (PCDots-C3N4) photocatalyst with phosphorus-nitrogen (P–N) bridging was prepared. The 13C and 31P of nuclear magnetic resonance, X-ray photoelectron spectroscopy, and density functional theory calculations confirmed the formation of a P–N bridge. Additionally, implanting PCDots enlarged the π-π conjugated electronic structure and modulated the plane structure of g-C3N4. The atomic-level connection by the P–N bridge dramatically extended the delocalization effect and facilitated the intramolecular charge transfer. PCDots-C3N4 demonstrated efficient photodegradation of tetracycline hydrochloride (TC) and bisphenol A (BPA) than both g-C3N4 and CDots-C3N4, reaching 76% and 100%, respectively. The possible degradation pathways of TC and BPA were also discussed. This work provides an efficient strategy for rapid electron transfer to form a new paradigm for wastewater remediation.
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