化学
环加成
立体化学
键裂
药物化学
芳基
分子
衍生工具(金融)
劈理(地质)
组合化学
有机化学
催化作用
烷基
岩土工程
断裂(地质)
金融经济学
工程类
经济
作者
Subrata Biswas,Surajit Duari,Srabani Maity,Arnab Roy,Asma M. Elsharif,Srijit Biswas
摘要
A reaction between 2-alkoxynaphthalene and an in situ formed azaoxyallyl cation has been reported under ambient reaction conditions. The (3 + 2) cycloaddition reaction followed by aryl C-OMe/C-OEt bond cleavage produces a variety of benzo[e]indolone derivatives. Based on the isolated intermediate from the control experiment and previous results, a possible mechanism has been drawn. Reduction of the N-O bond of the benzo[e]indolone derivative manifests the possibility of further functionalization of the products towards biologically important heterocyclic molecules.
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