Photoredox-Catalyzed Trifluoromethylamination of Alkenes with Concomitant Introduction of a Quinoxalin-2(1H)-one Moiety

A photoredox-catalyzed strategy for the difunctionalization of alkenes with quinoxalin-2(1H)-ones and N-CF3 hydroxylamine reagents was developed. This reaction was carried out under photoirradiation conditions, affording the corresponding three-component coupling products in moderate to high yields with excellent regioselectivity. It provides a new protocol to access valuable quinoxalin-2(1H)-one derivatives containing a N-CF3 group.