Benchmark Paraffin Adsorption in a Super‐Hydrophobic Porous Coordination Polymer with Blade‐Like Circular Phenyl Nanotraps

Abstract Selective capture of paraffin from olefin that permits one‐step purification of olefin is significantly important, yet developing adsorbents with high selectivity and hydrophobicity remains a daunting challenge. Although aromatic environments can enhance paraffin affinity and hydrophobicity through nonpolar interactions, water adsorption still occurs in regions distant from the aromatic rings, as well as in secondary pores that are always overlooked. Herein, we reported an ultramicroporous porous coordination polymer (ZnFPCP) featuring blade‐like circular phenyl paraffin nanotraps. As further validated by density functional tight binding (DFTB) calculations, grand canonical Monte Carlo (GCMC) simulations, and in situ Fourier‐tansform infrared absorption (FT‐IR) analysis, these ultramicroporous paraffin nanotraps created by surrounding benzene rings enhance the paraffin‐selective adsorption, and the segmented spaces between adjacent nanotraps in the blade‐like structure, combined with hydrophobic petal‐like secondary pore channels enclosed by fluorinated functional groups, further mitigate the water co‐adsorption. Remarkably, ZnFPCP exhibited outstanding ideal adsorption solution theory (IAST) selectivity (C 3 H 8 /C 3 H 6 : 2.08, C 2 H 6 /C 2 H 4 : 2.93) under ambient conditions and record‐breaking C 3 H 8 /C 2 H 6 uptake at low pressures. Breakthrough experiments demonstrated the excellent performance of ZnFPCP in olefin purification, affording the exceptional productivity of ultra‐high purity (99.99%) for C 3 H 6 and C 2 H 4 . Robust stability and super hydrophobicity highlight its potential in harsh industrial application scenarios.