High-stretchable, self-healing, self-adhesive, self-extinguishing, low-temperature tolerant starch-based gel and its application in stimuli-responsiveness

Starch with active hydroxyl groups is one of the most attractive carbohydrates for the preparation of gels in recent years. However, the mechanical properties, self-healing properties, self-adhesion properties, especially low-temperature resistance are generally unsatisfactory for current starch-based gels. Based on that, a multiple network structure of amylopectin-carboxymethyl cellulose-polyacrylamide (ACP) gel was prepared by a "cooking" method. Tannic acid (TA) was used to construct multiple hydrogen bonds among molecular chains. ACP gel demonstrates high elongation at break (1090 %) and strength, self-healing performance and adhesion behavior, extraordinary low-temperature resistance (-80 °C) and self-extinguishing. As a sensor device, ACP gel can effectively monitor human movements and microscopic expression changes and achieve real-time monitoring under harsh conditions (After multiple cutting-healing steps, under low-temperature conditions, even a month later). Additionally, ACP gel could be served to detect temperature changes with a wide operating range and a high sensitivity of 33 %·°C-1, which is promising to monitor the changes in temperature. More interestingly, ACP gel can even monitor the cooking process and breathing frequency with fast response, implying applications in food processing, disease diagnosis and medical treatment. This study provides new opportunities for the design and fabrication of carbohydrate-based gels with multiple performance and multifunctional electronic devices.