Visible-light-driven electron donor–acceptor complex induced sulfonylation of diazonium salts with sulfinates
电子转移
光催化
氧化还原
作者
Xin Liang,Yufei Li,Qing Xia,Lan Cheng,Jianbo Guo,Pei Zhang,Weihua Zhang,Qingmin Wang
出处
期刊:Green Chemistry [The Royal Society of Chemistry] 日期:2021-11-16卷期号:23 (22): 8865-8870被引量:1
标识
DOI:10.1039/d1gc03239a
摘要
This work reports an efficient sulfonylation reaction enabled by a visible-light-induced radical coupling reaction between phenyl/heterocyclic diazonium salts and sulfinates. Mechanistic experiments disclosed the formation of a versatile electron donor–acceptor (EDA) complex. This transformation is characterized by an easy operational procedure under mild conditions which avoids transition metals, ligands, catalysts, and oxidants.