催化作用
甲烷
钙钛矿(结构)
X射线光电子能谱
价(化学)
柠檬酸
燃烧
粒径
无机化学
超细粒子
化学工程
氧气
材料科学
化学
物理化学
结晶学
纳米技术
有机化学
工程类
作者
Ziyi Zhong,Kaidong Chen,Yong Ji,Qijie Yan
标识
DOI:10.1016/s0926-860x(97)00003-3
摘要
Ultrafine perovskite-type complex oxides LaFe1−yAyO3−λ (A = Mn, Al, Co) were prepared by sol-gel method using citric acid as complex agent, and characterized by XRD, TPR, TG and XPS techniques. The catalytic activities for methane combustion were tested and compared with that of the large particle oxides having the same composition. It was shown that the catalytic activities of ultrafine LaFe1−yAyO3−λ complex oxides were much higher than that of LaFeO3 sample due to the increase of high valence B-site cations and lattice oxygen content by the substitution of B-site elements. Much higher catalytic activities were also observed for the ultrafine perovskite-type complex oxides compared to their large particle counterparts.
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