化学
高价分子
碘苯
黄烷酮
甲酰化
芳基
立体化学
碘
有机化学
催化作用
抗氧化剂
类黄酮
烷基
作者
László Juhász,László Szilágyi,Sándor Antus,Júlia Visy,Ferenc Zsila,Miklós Simonyi
出处
期刊:Tetrahedron
[Elsevier]
日期:2002-05-01
卷期号:58 (21): 4261-4265
被引量:39
标识
DOI:10.1016/s0040-4020(02)00360-5
摘要
Flavanone (1) on oxidation with iodobenzene diacetate (PIDA) in the presence of sulfuric acid in trimethyl orthoformate (TMOF) undergoes a stereospecific ring contraction by an aryl shift to result in trans methyl 2-aryl-2,3-dihydrobenzo[b]furan-3-carboxylate (4a) as a major product. The mechanism of this transformation has been discussed on the basis of NMR, CD and chiral HPLC evidence.
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