超级电容器
材料科学
杂原子
电解质
化学工程
介孔材料
碳纤维
电化学
法拉第效率
电流密度
电容
多孔性
碳化
比表面积
纳米技术
电极
化学
催化作用
复合材料
扫描电子显微镜
有机化学
戒指(化学)
物理化学
工程类
物理
复合数
量子力学
作者
Chenggui Tang,Yijiang Liu,Dong Yang,Mei Yang
出处
期刊:Carbon
[Elsevier]
日期:2017-10-01
卷期号:122: 538-546
被引量:88
标识
DOI:10.1016/j.carbon.2017.07.007
摘要
Heteroatom-doped porous carbons have currently been regarded as the promising materials for supercapacitors because of their outstanding contributions in Faradaic capacitance and electrolyte accessibility. In the present study, O/N co-doped porous carbons have been prepared by carbonization of ammonium citrate single precursor followed by KOH activation. The as-synthesized carbon (ACA-800) has a finely-layered schistose architecture together with a high surface O and N-containing functionalities (6.82 at.% O and 1.37 at.% N), a high micropore surface area (1522 m2 g−1) and a balanced mesopore surface area (1138 m2 g−1). Due to their synergistic effects, the ACA-800 electrode displays high-rate capacitive performance with specific capacitance of 297 F g−1 at 100 A g−1, at least 85% of its capacitance (349 F g−1) at 1 A g−1. Moreover, symmetric supercapacitor assembled with such ACA-800 exhibits high energy density of 25.5 W h kg−1 at 923 W kg−1 as well as excellent cycling stability (only 4% of capacitance loss after 10000 cycles with a cell voltage of 1.8 V at a current load of 2 A g−1). Considering the global abundance and low price of ammonium citrate, it can serve as a novel precursor for the mass production of O/N-enriched porous carbons for advanced supercapacitors.
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