铕
检出限
水溶液中的金属离子
发光
离子
金属有机骨架
材料科学
荧光
光化学
化学
分析化学(期刊)
配体(生物化学)
镧系元素
金属
物理化学
光电子学
有机化学
光学
受体
吸附
色谱法
物理
生物化学
作者
Yuming Zhao,Jinhui Liu,Sha Wang,Xu Zhai,Lei Shao,Yunling Liu,Xuemin Zhang,Junyi Chen,Fanbao Meng,Yu Fu
出处
期刊:Dalton Transactions
[The Royal Society of Chemistry]
日期:2021-01-01
卷期号:50 (39): 13823-13829
被引量:9
摘要
A dual-emissive optical material as a ratiometric fluorescent probe has been demonstrated to be remarkably superior in precise and quantitative analyses. Herein, a novel dual-emissive fluorescent probe Eu-BDC-OH was designed and successfully synthesized using Eu3+ and 2-hydroxyterephthalic acid (H2BDC-OH) at room temperature. Eu-BDC-OH has a three-dimensional interpenetrating network structure with a large number of exposed hydroxyl functional groups, providing abundant active sites for molecular recognition. In particular, the as-obtained Eu-BDC-OH serves as a unique fluorescent probe, and the double emission peaks of both the ligand and Eu3+ are completely quenched by Fe3+. However, it is worth noting that the dual emissions of Eu-BDC-OH enable the ratiometric detection of Fe2+, which leads to an increase in ligand emission and a decrease in Eu3+ emission, accompanied by a distinct red to blue color transition. The relative fluorescence intensity ratio (I618 nm/I433 nm) decreased linearly with increasing Fe2+ concentration in the 0-50 μM range with a superior detection limit of 0.32 μM. In this work, a fluorescent probe based on a MOF was developed for the recognition of Fe2+ and Fe3+, providing a promising strategy for the synthesis of novel dual-emission materials by integrating suitable luminescent ligands with lanthanide metal ions.
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