化学
SN2反应
亲核细胞
戒指(化学)
立体化学
瓦尔登反转
硅
计算化学
药物化学
有机化学
催化作用
作者
Robert J. P. Corriu,G. F. Lanneau,D. Leclercq
标识
DOI:10.1016/s0040-4039(00)88331-8
摘要
SN2(P) reactions of chlorophosphates, which take place with inversion of configuration, are highly dependent upon the nature of the nucleophile. On the contrary, exocyclic substitutions of five-membered ring chlorophosphates with retention show a marked kinetic levelling effect.
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