Recent Advances in the Synthesis of Commercially Available Phosphite Antioxidants

Abstract Phosphite antioxidants exhibit superior anti‐aging and color‐stabilizing properties when incorporated into polymer materials. Their synergistic antioxidative effects are particularly noteworthy when used in combination with hindered phenol antioxidants and other primary antioxidants, serving as effective secondary antioxidants, displaying noteworthy synergistic antioxidation effects. This review systematically classifies the synthetic methods for phosphite antioxidants into three distinct categories based on the types of starting materials: synthesis from phosphorus trichloride, phosphorus‐containing esters, and white phosphorus. Additionally, it delineates the reaction mechanisms associated with these approaches and provides an overview of future potential research directions and applications for organophosphorus antioxidants.