碳酸丙烯酯
二茂铁
电化学
水溶液
二甲基甲酰胺
化学
无机化学
电子转移
电解质
支撑电解质
分解
电极
光化学
有机化学
溶剂
物理化学
作者
A. J. Zara,Sérgio S. Machado,L.O.S. Bulhões,Assis Vicente Benedetti,T. Rabockai
出处
期刊:Journal of electroanalytical chemistry and interfacial electrochemistry
[Elsevier]
日期:1987-04-01
卷期号:221 (1-2): 165-174
被引量:39
标识
DOI:10.1016/0022-0728(87)80254-1
摘要
the electrochemical oxidation of ferrocene on Pt in dimethylformamide, ethanol, propylene carbonate and their aqueous solutions was studied at 25°C. The concentration of the supporting electrolyte, NaClO4, was varied from 0.1 to 0.5 M. The results show that the electrode process may be described as a quasi-reversible one-electron charge transfer, followed by slow decomposition of the oxidized species.
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