钙钛矿(结构)
四方晶系
纳米棒
卤化物
材料科学
光致发光
光电子学
光伏
纳米技术
光伏系统
化学
结晶学
无机化学
晶体结构
生态学
生物
作者
Sigalit Aharon,Lioz Etgar
出处
期刊:Nano Letters
[American Chemical Society]
日期:2016-04-25
卷期号:16 (5): 3230-3235
被引量:166
标识
DOI:10.1021/acs.nanolett.6b00665
摘要
Organo-metal halide perovskite is an efficient light harvester in photovoltaic solar cells. Organometal halide perovskite is used mainly in its “bulk” form in the solar cell. Confined perovskite nanostructures could be a promising candidate for efficient optoelectronic devices, taking advantage of the superior bulk properties of organo-metal halide perovskite, as well as the nanoscale properties. In this paper, we present facile low-temperature synthesis of two-dimensional (2D) lead halide perovskite nanorods (NRs). These NRs show a shift to higher energies in the absorbance and in the photoluminescence compared to the bulk material, which supports their 2D structure. X-ray diffraction (XRD) analysis of the NRs demonstrates their 2D nature combined with the tetragonal 3D perovskite structure. In addition, by alternating the halide composition, we were able to tune the optical properties of the NRs. Fast Fourier transform, and electron diffraction show the tetragonal structure of these NRs. By varying the ligands ratio (e.g., octylammonium to oleic acid) in the synthesis, we were able to provide the formation mechanism of these novel 2D perovskite NRs. The 2D perovskite NRs are promising candidates for a variety of optoelectronic applications, such as light-emitting diodes, lasing, solar cells, and sensors.
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