Facile generation of CeO2 nanoparticles on multiphased NiSx nanoplatelet arrays as a free-standing electrode for efficient overall water splitting

Constructing nanostructured electrocatalysts with heterointerface and finetuning their electronic properties are essential for high-efficient overall water splitting. Here, we prepared a well-designed nano-flower-like multiphase and hybrid material of NiS/NiS2/CeO2/NF (NiSx/CeO2/NF) with rich heterointerfaces and abundant active sites through solvothermal reaction and post-annealing treatment. The as-fabricated NiSx/CeO2/NF exhibits exceptional catalytic performance for OER and HER. Specifically, in 1 M KOH solution, it requires the low overpotentials of 326 and 92 mV to achieve the current density of 200 and 10 mA cm-2 for oxygen evolution reaction (OER) and hydrogen evolution reaction (HER), respectively. More satisfactorily, when NiSx/CeO2/NF is used as the bifunctional catalyst, a low voltage of only 1.53 V is required to achieve a current density of 10 mA cm-2 for overall water splitting. The excellent catalytic performance should be attributed to its special heterogeneous structure and the synergy effect between NiSx and CeO2. This work emphasizes the important significance of constructing efficient bifunctional electrocatalysts by reasonably designing heterostructures and multiphase components for overall water splitting.