Stereoselective Production of Imino‐d‐ribitol and C‐Azanucleosides through Electrochemical C−H Functionalization

Abstract Herein, we report a practical method for de novo preparation of imino‐ d ‐ribitol and C ‐azanucleosides. The diastereopure Imino‐ d ‐ribitol was synthesized on a multigram scale by simple manipulation, and late‐stage anomeric derivatization by regio‐ and diastereoselective electrochemical C(sp 3 )−H activation enabled the efficient synthesis of the corresponding C ‐azanucleosides with high β‐selectivity.