纳米团簇
荧光
检出限
碳纤维
纳米技术
材料科学
自来水
光化学
分析化学(期刊)
化学
线性范围
选择性
光学
色谱法
物理
复合材料
催化作用
有机化学
环境工程
工程类
复合数
作者
Lingling Yan,Jiaming Li,Hongxin Cai,Yang Shao,Guoxiang Zhang,Liang Chen,Yongqiang Wang,Haitao Zong,Yuehong Yin
标识
DOI:10.1016/j.jallcom.2023.169227
摘要
A fluorescent probe, N-doped carbon dots/Ag nanoclusters (N-CDs/AgNCs), was designed and synthesized successfully based on fluorescence inner filler effect (IFE) for the ratiometric and visual detection of Cu2+. Due to the IFE, the as-prepared probe exhibited a weak blue emission at 455 nm and a strong red emission and 665 nm. After adding Cu2+, the red fluorescence can be quenched because of the strong chelating interaction between GSH and Cu2+, whereas the blue fluorescence could be recovered because of the weakening of the IFE, accompanying by a remarkable fluorescence color change from pink to blue under a UV light. Under optimized experimental conditions, the N-CDs/AgNCs probe showed excellent selectivity to Cu2+ and a good linear relationship between the fluorescence intensity proportion (I665/I455) and Cu2+ concentration in the range of 0–60 μM with a detection limit of 0.13 µM. Further, N-CDs/AgNCs could be used for detecting Cu2+ in tap water and lake water. These results showed that the IFE ratiometric fluorescent probe may provide a new idea for the visualization and semiquantitative detection of Cu2+ and imply that it has great potential to detect Cu2+ in real environment water samples.
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