Preparation of Carborane-Tailored Covalent Organic Frameworks by a Postsynthetic Modification Strategy as a Barrier to Polysulfide in Lithium–Sulfur Batteries

Lithium–sulfur batteries (LSBs) have attracted much attention due to their high energy density and theoretical specific capacity. However, the "shuttle effect" of polysulfides limits their application. Herein, we propose a postsynthetic modification (PSM) strategy to synthesize a fibrous carborane-tailored covalent organic framework (PMCB-COF). Benefiting from its amphiphilicity, strong adsorption ability, high specific surface area, and accessible Li+ transport channels, PMCB-COF could serve as a barrier to polysulfide to inhibit the shuttle effect. The cell assembled with PMCB-COF exhibits a high initial capacity of 926 mAh g–1 at 1 C. A Coulombic efficiency of 98% and a fading rate of only 0.039% per cycle are exhibited even after 1500 cycles. So far as we know, PMCB-COF is one of the best materials as a separator of LSBs. This work provides a safe and efficient avenue for tailoring COFs with carborane and might help promote the development of secure, low-cost, and durable rechargeable batteries.