Enhancement of the hydrophobicity and oleophobicity of a polyurethane coating using a fluorine‐free polyfarnesene‐based polyol

Abstract The development of hydrophobic and oleophobic surfaces on materials has attracted significant attention in various research fields. Fluoropolymers, which possess low surface energy and are both highly hydrophobic and oleophobic in nature, are widely used to enhance the liquid repellency of materials. However, during fluoropolymer manufacture, fluorine‐containing compounds are released into the environment; thus, alternatives to fluoropolymers are required for maintaining environmental safety and realizing a sustainable society. Notably, the development of such alternative materials has been limited. Thus, we herein report the application of a novel polyurethane (PU) coating synthesized from bio‐based raw materials. The prepared hydrogenated polyfarnesene PU (HHPF PU), which possesses an amorphous bottlebrush‐like polyalkyl structure, was found to exhibit higher hydrophobicity and oleophobicity than polytetrafluoroethylene (PTFE), which is a typical low‐surface‐energy material. The water and n ‐hexadecane contact angles of the HHPF PU were determined to be 119° and 68°, respectively, whereas those of PTFE were 108° and 46°, respectively. In addition, the density depth profile of the PU thin film was confirmed through x‐ray reflectometry. This study provides a novel approach for enhancing the hydrophobicity and oleophobicity of materials using bottlebrush‐like polyalkyl structure instead of fluorine.