膜
微型多孔材料
聚酰胺
化学工程
材料科学
共价有机骨架
选择性
渗透
无机化学
共价键
化学
高分子化学
有机化学
渗透
复合材料
工程类
催化作用
生物化学
作者
Zhenshu Si,Zhe Zhang,Congcong Yin,Tao Ju,Mingjie Wei,Jun Huang,Yong Wang
标识
DOI:10.1016/j.memsci.2023.121759
摘要
Microporous polyamide membranes that allow lithium ions to pass through easily but exclude magnesium ions hold vast potential in the lithium extraction from brine lakes. The efficacy, nevertheless, has long been limited by a trade-off that the magnesium/lithium selectivity is received at the expense of the permeability, arising from the highly cross-linked polyamide. This work describes that rationally lowering the internal density of polyamides by embedding functionalized covalent organic framework (COF) nanosheets can boost the selectivity and permeability simultaneously. A cationic COF, TpTGCl, is used to build transport highways in membranes, which shows the double role that not only lowers the polyamide density in a controllable way, but also strengthens the positive charge property. The resulting membrane exhibits a large water permeance of 19.6 L m−2 h−1 bar−1, along with an excellent separation factor of up to 21.3 under a high magnesium/lithium ratio of 30. This engineering strategy offers a means by which charged and nanoporous two-dimensional frameworks can be leveraged as a booster for microporous membranes enabling fast and precise ion transports.
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