Exploring the Sr2Ga2GeO7:Tb3+ Long Persistent Luminescence Phosphor for Cutting‐Edge Forensic Solutions in Latent Fingerprint Detection and Anticounterfeiting Applications

Abstract A series of Sr 2‐x Ga 2 GeO 7 : x Tb 3+ (0 mol% ≤ x ≤ 10 mol%) phosphors exhibiting persistent luminescence is synthesized via a high‐temperature solid‐state reaction. Structural analysis and phase identification are conducted using X‐ray powder diffraction and Rietveld refinement. The reflectance spectra revealed that the synthesized phosphor exhibited a direct bandgap with a value of 4.99 eV. The photoluminescence excitation spectra displayed broad absorption bands corresponding to the 4f 8 → 4f 7 5d 1 transition of the Tb 3+ ion, along with narrow‐band absorption peaks attributed to the 4f‐4f transitions. The emission spectra featured peaks resulting from transitions from the excited energy‐state ( 5 D 3 / 5 D 4 ) to the ground‐state levels ( 7 F J ). Among these transitions, the 5 D 4 → 7 F 5 transition is dominant, producing the green emission of the synthesized phosphor. Concentration quenching is observed, attributed to the radiative reabsorption process. Additionally, the synthesized phosphor demonstrated thermal stability up to 675 K. The kinetic scan and afterglow measurements showed that the persistent luminescence lifetime is ≈7000 s, and the afterglow persistence is up to 100 s. Thermoluminescence measurements revealed that besides the intrinsic defect, doping introduced the interstitial and vacancy defects that contributed to improving the persistent luminescence of the synthesized phosphor. The synthesized phosphor demonstrated a practical application for latent fingerprint detection and anticounterfeiting applications.