超级电容器
材料科学
聚苯胺
乙烯醇
电解质
电极
电化学
纳米技术
复合材料
弯曲
化学工程
电容
聚合物
聚合
化学
工程类
物理化学
作者
Wei Li,Xiaofeng Li,Xintao Zhang,Jing Wu,Xiaohan Tian,Mei-Jiao Zeng,Jin Qu,Zhong‐Zhen Yu
出处
期刊:ACS applied energy materials
[American Chemical Society]
日期:2020-08-20
卷期号:3 (9): 9408-9416
被引量:62
标识
DOI:10.1021/acsaem.0c01794
摘要
Although supercapacitors attract tremendous attention due to their high power density, long cycle life, and high efficiency, it is still a challenge to prepare flexible and wearable supercapacitors with stable electrochemical performances during bending, twisting, and stretching. Herein, a vertically aligned and physically cross-linked poly(vinyl alcohol)–H2SO4 hydrogel (APH) film is fabricated by freezing–thawing and directional-freezing approaches, and polyaniline (PANI) is subsequently grown in situ on both sides of the APH film to generate a flexible and conductive APH–PANI film with vertically aligned channels as both polymeric electrodes and electrolyte of an integrated supercapacitor. The APH–PANI supercapacitor exhibits an outstanding specific capacitance of 25.86 mF cm–2 at a current density of 0.05 mA cm–2, 4.65 times its counterpart with a random network, because of the rapid transport of ions within the aligned channels between the two electrodes, which remains at 94% after 2000 charge/discharge cycles. More importantly, the APH–PANI supercapacitor not only presents excellent flexibility and stable electrochemical performances during twisting, bending, and stretching but also exhibits a superior self-healable capability by reorganizing dynamic hydrogen bonding. Thanks to the unique structure, high performance, and mechanical stability, the integrated APH–PANI supercapacitor shows a great potential for high-performance flexible devices.
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