化学
催化作用
吸附
环加成
锌
路易斯酸
碳酸丙烯酯
无机化学
有机化学
物理化学
电极
电化学
作者
Yixing Li,Xiao Zhang,Jianwen Lan,Ping Xu,Jianmin Sun
出处
期刊:Inorganic Chemistry
[American Chemical Society]
日期:2019-09-27
卷期号:58 (20): 13917-13926
被引量:67
标识
DOI:10.1021/acs.inorgchem.9b01762
摘要
An efficient Zn(Bmic)(AT) MOF with available Lewis acid–base blocks was prepared by a solvothermal method combining the mixed ligands 5-aminotetrazole (HAT) and 1-benzimidazole-5-carboxylic acid (H2Bmic). The prepared Zn(Bmic)(AT) catalyst is rich in amino groups, uncoordinated oxygen atoms, and multiple open metal sites (OMSs), which contribute to CO2 adsorption of 79 cm3/g at 273 K and 52 cm3/g at 298 K, with high adsorption enthalpy (28 kJ mol–1). Furthermore, its multiple functional sites facilitate CO2 cycloaddition to various small-molecule epoxides to give five-ring cyclic carbonates with the assistance of a Bu4NBr cocatalyst, achieving a high TON of 170 for propylene carbonates (PC) under solvent-free, mild conditions (80 °C, 5 bar). In addition, the Zn(Bmic)(AT) catalyst exhibits good recyclability for six consecutive cycles. Moreover, a feasible synergistic mechanism of Zn(Bmic)(AT)/Bu4NBr catalysts for CO2 conversion into cyclic carbonate is proposed.
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