渗透
纳滤
膜
化学工程
薄膜复合膜
界面聚合
反渗透
聚酰胺
海水淡化
化学
水溶液
色谱法
相位反转
材料科学
核化学
高分子化学
有机化学
聚合物
渗透
生物化学
工程类
单体
作者
Congcong Liu,Xingtao Zuo,Qiyuan Wu,Juan Xiong,Jiajie He,Yun Zhou,Cong Ma,Zhongbing Chen,Shuili Yu
出处
期刊:Desalination
[Elsevier]
日期:2021-12-01
卷期号:520: 115335-115335
被引量:33
标识
DOI:10.1016/j.desal.2021.115335
摘要
Ultra-thin loose thin-film composite (TFC) nanofiltration membrane with potential high permeability is an urgent need in water purification. However, its tailor-made structure and morphology remains a challenge. Herein, a novel composite membrane was proposed for the first time by introducing 3,5-diamino-1,2,4 triazole (GAZ) and piperazine with trimesoyl chloride (TMC) into polyamide layer. The physic-chemical properties of the membranes prepared with various GAZ concentrations in the aqueous phase were characterized. GAZ-incorporated membranes had a thinner active layer and larger pore sizes as well as smoother surface morphology with increasing GAZ content. The presence of GAZ made the pure water permeance of the membranes 2.3-folds of the typical TFC membrane without GAZ, up to 30.5 LMH/bar with a comparable Na2SO4 rejection of 93.5%. The membranes fabricated with a higher GAZ fraction exhibited superior removal for the dyes of Rose bengal (>99.6%) and Congo red (>97.5%) with the dye permeance over 23.0 LMH/bar, and higher rejection rates for natural organic matters (>98.5%, >98.0% and >93.0% for sodium alginate, bovine serum albumin and humic acid, respectively). The membranes with stable operation implied their potential applications in water desalination and purification.
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