化学
乙腈
臭氧分解
三苯胺
电化学
电催化剂
产量(工程)
水溶液
光化学
阳极氧化
阳极
有机化学
电极
材料科学
物理化学
冶金
作者
Xin Wu,and Anthony P. Davis,Albert J. Fry
出处
期刊:Organic Letters
[American Chemical Society]
日期:2007-11-30
卷期号:9 (26): 5633-5636
被引量:73
摘要
A series of symmetrical and unsymmetrical stilbenes bearing two or more strong electron-withdrawing groups were oxidatively cleaved to the corresponding aldehydes in high yield by electrocatalytic anodic oxidation in aqueous acetonitrile employing a new high oxidation potential triphenylamine electrocatalyst. The oxidations apparently involve the corresponding 1,2-diols, which are also converted to aldehydes in high yield under the same conditions.
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