等结构
化学
亚稳态
介孔材料
金属有机骨架
吸附
金属
无机化学
结晶学
晶体结构
有机化学
吸附
催化作用
作者
Yabing He,Zhiyong Guo,Shengchang Xiang,Zhangjing Zhang,Wei Zhou,Frank R. Fronczek,Sean Parkin,Stephen T. Hyde,M. O’Keeffe,Banglin Chen
出处
期刊：Inorganic Chemistry
[American Chemical Society]
日期：2013-09-25
卷期号：52 (19): 11580-11584
被引量：66
摘要
Three isostructural interwoven 3,4-connected mesoporous metal-organic frameworks of pto-a topology (UTSA-28-Cu, UTSA-28-Zn, and UTSA-28-Mn) were synthesized and structurally characterized. Because of their metastable nature, their gas sorption properties are highly dependent on the metal ions and activation profiles. The most stable, UTSA-28a-Cu, exhibits promising gas storage and separation capacities.
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