化学
分子内力
亲核细胞
组合化学
分子间力
功能群
氧化磷酸化
盐(化学)
有机化学
分子
催化作用
生物化学
聚合物
作者
Jun Jiang,Ting Xiong,Xingcui Zhou
摘要
A highly efficient oxidative dearomatization of indoles with H-phosphorus oxides in the presence of TEMPO oxoammonium salt has been demonstrated. Through the intramolecular oxidative dearomatization of indoles and subsequent intermolecular nucleophilic addition with phosphorus nucleophile, a variety of structurally diverse arylphosphoryl and alkylphosphoryl indolin-3-ones were obtained in good yields with a broad substrate scope and high functional-group compatibility.
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