钯
化学
偶联反应
Atom(片上系统)
催化作用
组合化学
有机化学
计算机科学
并行计算
作者
Man-Tak Leung,Yi Ling Tsang,Pui Ying Choy,Fuk Yee Kwong
标识
DOI:10.1002/9783527834242.chf0157
摘要
Abstract The advancement of CH/CH cross‐dehydrogenative coupling (CDC) reactions for the construction of C(sp 2 )C(sp 2 ) bond with representative examples from mainly 2016 to May 2021 is overviewed. Palladium‐catalyzed CDC reaction has been considered as a modern and attractive synthetic tool due to (i) limited amount of undesired and toxic by‐products; (ii) more straightforward synthetic approach from simple materials, resulting in a better step‐ and atom economy. Diversified applications across pharmaceutical and material areas have been successfully realized. In addition to the ordinary CDC reaction, the most recent accomplishments of asymmetric CDC process are also included.
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