带隙
材料科学
钝化
钙钛矿(结构)
光电子学
串联
晶界
结晶
异质结
纳米技术
化学工程
化学
结晶学
冶金
图层(电子)
复合材料
微观结构
工程类
作者
Hai Wang,Jingsheng He,Huimin Xiang,Ran Ran,Wei Zhou,Wei Wang,Zongping Shao
出处
期刊:Energy & Fuels
[American Chemical Society]
日期:2023-04-17
卷期号:37 (9): 6401-6423
被引量:10
标识
DOI:10.1021/acs.energyfuels.3c00462
摘要
Low-cost perovskite solar cells (PSCs) with high power conversion efficiencies (PCEs) of >25% are considered as the most promising replacement for commercial silicon-based solar cells to realize a sustainable future. To break the theoretical PCE limits of single-junction PSCs, all-perovskite tandem solar cells consisting of a narrow-band-gap bottom subcell and a wide-band-gap top subcell have attracted particular attention recently. Mixed Pb–Sn perovskites with narrow band gaps have received great attention as an efficient light harvester in the bottom subcell of all-perovskite tandem solar cells as a result of the reduced toxicity, high light-absorbing capability, and matched current with the wide-band-gap top subcells. However, mixed Pb–Sn narrow-band-gap PSCs suffer from low PCEs, inferior stability, and high open-circuit voltage (Voc) loss, owing to the high defect amount and inferior perovskite film quality induced by the detrimental oxidation of Sn2+ cations and the rapid crystallization of perovskite crystals. Herein, the recent advances about the additive engineering for mixed Pb–Sn narrow-band-gap PSCs are reviewed by demonstrating the origins and unique features of Pb–Sn narrow-band-gap perovskites. Additionally, several strategies to improve PCEs and durability of Pb–Sn narrow-band-gap PSCs through additive engineering are proposed, including Sn2+ cation stabilization, heterojunction construction, crystallization control, surface/grain boundary passivation, film morphology control, carrier dynamics modulation, and gradient-distributed film formation. Furthermore, the existing challenges and future directions are also presented, aiming to provide important insights for designing and developing efficient and stable single-junction narrow-band-gap PSCs and all-perovskite tandem solar cells.
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