法拉第效率
材料科学
插层(化学)
电池(电)
阴极
重量分析
纳米材料
硫黄
化学工程
氧化还原
电化学
纳米技术
锂(药物)
储能
无机化学
电极
冶金
有机化学
化学
物理化学
医学
量子力学
功率(物理)
内分泌学
工程类
物理
作者
Shiqi Xu,Chun Yuen Kwok,Laidong Zhou,Zhizhen Zhang,Ivan Kochetkov,Linda F. Nazar
标识
DOI:10.1002/adfm.202004239
摘要
Abstract As demands for electrochemical energy storage continue to rise, alternative electrochemistries to conventional Li‐ion batteries become more appealing. Here, an intercalation‐conversion hybrid cathode that combines intercalation‐type VS 2 with conversion‐type sulfur chemistry to construct high performance solid‐state lithium‐sulfur batteries is reported. The layered VS 2 nanomaterial features Li‐ion transport channels, metallic conductivity, and active capacity contribution, all of which provide an ideal platform for the solid state S/Li 2 S redox couple to unlock its high gravimetric capacity. The S/VS 2 /Li 3 PS 4 hybrid cathode composite is prepared by a facile, low‐cost, and low‐energy mechanical blending process. The S/VS 2 /Li 3 PS 4 |Li 3 PS 4 |Li/In (or Li) all‐solid‐state cell exhibits sulfur utilization of ≈85%, with a Coulombic efficiency of close to 100%. High areal capacity up to 7.8 mA h cm −2 with an active material loading (S/VS 2 ) as high as 15.5 mg cm −2 is achieved.
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