Synthesis of Pt-Loaded NiFe-LDH Nanosheets on Wood Veneer for Efficient Gaseous Formaldehyde Degradation

甲醛 材料科学 催化作用 单板 降级(电信) 化学工程 复合数 吸附 热液循环 环境污染 复合材料 有机化学 化学 环境保护 工程类 电信 计算机科学 环境科学
作者
Tailong Cai,Ping Zhang,Xiaoyuan Shen,Erzhuo Huang,Xiaoping Shen,Jiangtao Shi,Zhe Wang,Qingfeng Sun
出处
期刊:ACS Applied Materials & Interfaces [American Chemical Society]
卷期号:12 (33): 37147-37154 被引量:31
标识
DOI:10.1021/acsami.0c09016
摘要

Traditional methods of removing gaseous formaldehyde are often associated with high energy consumption and secondary pollution. In this study, a new wood veneer-based composite decorated with Pt-loaded NiFe-LDH nanosheets is successfully developed by a hydrothermal reaction and impregnation-chemical reduction. NiFe-LDH nanosheets as an adsorbent can capture formaldehyde molecules through their abundant hydroxyl groups. Pt nanoparticles as catalytic centers are evenly distributed on the surface of NiFe-LDH to excite the O atoms linked to NiFe-LDH and absorbed oxygen, which will further attack the absorbed formaldehyde molecules to generate CO2 and H2O. And the wood veneer not only increases the active area of the catalyst by endowing it with good dispersion but also provides convenient channels for reactants and products. In a simulated dark environment at room temperature, this synthetic wood veneer-based composite exhibits admirable catalytic activity, which can effectively degrade almost all gaseous formaldehyde with the initial concentration of 0.2 mg m-3 in 30 min and maintain a high catalytic activity of ≥97% after 10 cycles. This paper presents a feasible strategy for synthesizing an energy-efficient and ecofriendly wood veneer-based composite for efficient gaseous formaldehyde degradation at room temperature, which may play an important role in indoor air purification as a promising decorative material.

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