化学
碘
催化作用
环境友好型
分子氧
芳基
水溶液
有机化学
烯烃
组合化学
烷基
生态学
生物
作者
Bangqing Ni,Yunpeng He,Xuejiao Rong,Tengfei Niu
出处
期刊:Synlett
[Georg Thieme Verlag KG]
日期:2019-08-09
卷期号:30 (15): 1830-1834
被引量:7
标识
DOI:10.1055/s-0039-1690163
摘要
An environmentally friendly and efficient strategy has been developed for preparing β-hydroxy sulfides by a molecular-iodine-catalyzed radical reaction. This reaction involves hydroxysulfenylation of alkenes with disulfides in aqueous solution. Air is used as the oxidant without any additives. Control experiments indicated that the oxygen atom of products might come from O2. Both aryl alkenes and aliphatic alkenes were well tolerated in this transformation and afforded the corresponding products in moderate to high yields.
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