“ON-OFF-ON” fluorescence switches based on N,S-doped carbon dots: Facile hydrothermal growth, selective detection of Hg2+, and as a reversive probe for guanine

Water contamination due to heavy metal ions has become a major environmental problem worldwide. In this work, “on-off-on” fluorescence switches comprising N,S-doped carbon dots (N,S-CDs) have been developed for selective recognition of Hg2+ and as reversive probes for guanine. N,S-CDs were synthesized in a facile one-step hydrothermal approach using citric acid and methionine as precursors. The synthesized N,S-CDs display fluorescence with excitation/emission maxima of 370/440 nm and a quantum yield of 32.5%. Under the variable pH (2–12), the fluorescent N,S-CDs with a linear range from 0.05 to 100 μM displayed selective discrimination for Hg2+ with the limit of 6.24 nM over several other cations, anions, and neutral analytes resulting in the quenching of fluorescence response. Furthermore, the addition of guanine at the LOD of 6.4 nM can restore N,S-CDs' fluorescence in a reversible manner. For this kind of fluorescence switch, its purposed applications on environmental samples are employed successfully to detect Hg2+ in tap water and river water.