Meticulously tailoring phase boundary in KNN‐based ceramics to enhance piezoelectricity and temperature stability

Abstract Although KNN‐based ceramics with high electrical properties are obtained through a variety of strategies, the temperature sensitivity is still one of the key technical bottlenecks hindering practical applications. Here, we use a new strategy, meticulously tailoring phase boundary, to refine the ferroelectric boundary of KNN‐based ceramics, leading to high piezoelectricity companied with improving temperature stability. The highest d 33 value in this system reaches 501 pC/N with a T C ∼ 240°C, whereas a large strain of ∼0.134% can be kept with 10% lower deterioration until 100°C. The origin of high piezoelectricity is mainly attributed to the well‐preserved multiphase coexistence and the appearance of nanodomains, which greatly facilitate the polarization rotation. Instead of the changed intrinsic thermal insensitivity, the precision phase boundary engineering plays an important role in strengthening the temperature stability of electric‐induced strain. This work provides a simple and effective method to obtain both high electrical properties and excellent thermal stability in KNN‐based ceramics, which is expected to promote the practical applications in the future.