苯并咪唑
化学
超分子化学
抗菌活性
噻吩
氢键
核化学
大肠杆菌
最小抑制浓度
热重分析
结晶学
抗菌剂
晶体结构
细菌
立体化学
有机化学
分子
生物化学
基因
生物
遗传学
作者
Abdul Rauf,Junwei Ye,Aiyu Hao,Longmao Zhao,Siqi Zhang,Ye Qi,Lei Shi,Guiling Ning
标识
DOI:10.1080/00958972.2018.1510122
摘要
A silver(I) supramolecular network Ag(BIm)2(HTDC) (1) was assembled from thiophene-2,5-dicarboxylic acid (H2TDC) and benzimidazole (BIm) ligands and characterized by single-crystal X-ray diffraction, elemental analysis, FT-IR, and thermal gravimetric analysis. Complex 1 possesses a two-dimensional structure with a hydrogen-bonded grid network, in which the adjacent [Ag(BIm)2]+ cations and (HTDC)– are bridged via N–H···O hydrogen bonds forming undulating ribbons. The antibacterial properties of 1 were investigated by determining the minimal inhibitory concentration (MIC), the growth curve of bacteria and zone inhibition value assays against Gram-negative bacterium, Escherichia coli, and Gram-positive bacterium, Staphylococcus aureus. The MIC of 1 against E. coli and S. aureus are 15-20 ppm and 20-30 ppm which showed that 1 has higher antibacterial activity than commercial silver nanoparticles. The mechanism of antibacterial activity of 1 was also discussed.
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