环境化学
硫代硫酸盐
硫化物
硫循环
硫酸盐还原菌
硫化氢
二氧化硫
亚硫酸盐
氧化还原
黄铁矿
产甲烷
作者
Dongjin Wan,Yongde Liu,Wang Yiyi,Qi Li,Jingnan Jin,Shuhu Xiao
出处
期刊:Chemosphere
[Elsevier]
日期:2019-01-01
卷期号:215: 40-49
被引量:10
标识
DOI:10.1016/j.chemosphere.2018.10.006
摘要
Abstract This study investigates the sulfur (S) disproportionation tendencies in a sulfur packed bed reactor for perchlorate bio-autotrophic reduction at different temperatures. The reactor was operated with over 99% efficiency for 21.00 ± 1.40 mg L−1 perchlorate removal when the hydraulic retention time (HRT) ranged from 12.00 h to 0.75 h at 27 ± 2 °C. When HRT was controlled at 1.00 h, the perchlorate removal efficiency was only 8 ± 1% as the temperature dropped to 6 ± 1 °C. The half-order model fit both perchlorate removal and S disproportionation reaction well. Compared with S disproportionation, the decrease of temperature had a greater influence on perchlorate reduction. As the temperature dropped from 27 ± 2 °C to 6 ± 1 °C, the 1/2K1/2v,R for perchlorate reduction decreased from 7.37 mg1/2 L−1/2 h−1 to 0.19 mg1/2 L−1/2 h−1. Meanwhile, the 1/2K1/2v,S for S disproportionation decreased from 3.04 mg1/2 L−1/2 h−1 to 1.96 mg1/2 L−1/2 h−1. The reaction activation energy of perchlorate reduction and S disproportionation was 120.28 kJ mol−1 and 13.44 kJ mol−1, respectively. The S disproportionation reaction proceeded remarkably at the beginning of the reduction, a longer HRT and higher temperature promoted S disproportionation, resulting in excessive sulfate generation and alkalinity consumption. Besides, the spatial distribution of the microbial communities and the dominant bacteria function under different HRTs was analyzed using high-throughput sequencing.
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