A review and perspective of recent research in biological treatment applied in removal of chlorinated volatile organic compounds from waste air

Chlorinated volatile organic compounds (Cl-VOCs) waste air is a kind of typical recalcitrant organic compounds, which poses a great threat to the ecological environment and human health. At present, the biotechnology is considered as a potential strategy for the Cl-VOCs removal due to the advantages of low energy consumption and less possibility of secondary pollution. This work summarizes the recent researches on strains, bioreactors and technology integration. The dominant pure strains for biodegradation of Cl-VOCs are first outlined with a special focus on the co-metabolism of multi-components. It then summarizes two bioreactors (optimized airlift reactor (ALR) and two-phase partitioning bioreactor (TPPB)) and strategy (addition of surfactant) for improvement of biotrickling filter (BTF), which are benefit to achieve the mass transfer enhancement in the removal of hydrophobic Cl-VOCs from waste air. After that, the integration technologies, such as magnetic field (MF)-BTF, non-thermal plasma (NTP)/ultraviolet light (UV)-BTF, and microbial electrolytic cells (MEC), are elucidated, which provide opportunities for complete mineralization of Cl-VOCs in a more efficient, energy-saving and economical way. Finally, current challenges and a perspective of future research on biotechnology for Cl-VOCs removal are thoroughly discussed.