材料科学
扫描电子显微镜
涂层
X射线光电子能谱
阴极
图层(电子)
化学工程
电化学
介电谱
透射电子显微镜
复合材料
电解质
电极
纳米技术
化学
物理化学
工程类
作者
Yaohua Feng,Hui Xu,Bo Wang,Shimin Wang,Ling Ai,Shiyou Li
摘要
Abstract The Ni-rich LiNi0.8Co0.1Mn0.1O2 (NCM811) is considered as a promising high capacity (more than 160 mAh/g) cathode for lithium-ion batteries. However, NCM811 suffers the rapid capacity fading and potential safety hazard during cycling, which hinders further commercial application. Herein, a homogeneous Al2O3 film is successfully coated on the NCM811 surface by the liquid phase deposition. The Al2O3 coating layer is evidenced by X-ray diffraction, transmission electron microscopy, scanning electron microscopy, and X-ray photoelectron spectroscopy. The results clearly demonstrate that the Al2O3 film is uniformly covered on the NCM811. In particular, the 2 wt% Al2O3-coated materials delivers a high discharge capacity of 162.2 mAh/g and with retention of 82.67% after 100 cycles at 0.5 C than that of the pristine NCM811 electrode with retention of 64.90% and discharge capacity of 111.50 mAh/g. The improved electrochemical performance can be ascribed to the thin and dense coating layer not only effectively inhibits the direct contact between the material and the electrolyte but also promotes the transfer of Li+ in the layered structure material.
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